Can't create new user, always adds to 'invite' list

Can't create new user, always adds to 'invite' list

Whenever I try to create a particular user the system creates an invite for an existing user.
All other user names appear in the users list but this particular one won't.

I have checked all my existing users and their aliases and the address isn't already being used (as noted in a previous question)

Any help appreciated
Thanks