I see there are others that have encountered this problem recently. I will add so you can see they are apparently not isolated cases.
In my case, users recently began reporting unable to enter email on our website using Safari. When I tried it (I downloaded Safare to test, since I had not installed before), I also got failure. In my case the error reads: "Invalid entries found. Please correct and try again"
My FF & IE work OK with verification, Safari works when I remove verification
I googled "Captcha on Safari" and found several hits like this. One apparentlly found their fix by upgrading to Captcha version to 5.x-3.0-rc1. That website was http://drupal.org/node/169381.
Hope we can find the answer to this.