How can I add a new workflow rule for invoices module?

How can I add a new workflow rule for invoices module?

Hi, I'm going to develop new extension for invoices module.
I wanna call other API When save invoices record.
Hence, I have to add a new workflow  rule for invoices module.
But "Invoices" does not appear in the module list.

How can I call API When save invoices record?
If workflow rule didn't support for invoices module, please show me any other way.

Thanks