Is it possible to add a server for email relay when using a personal gmail account?

Is it possible to add a server for email relay when using a personal gmail account?

I'm having issues setting up a server for email relay.  Is it possible to add a server for email relay using a personal gmail account? I keep getting a message that authentication failed  I've verified that the email address and password are correct.  I've tried all combinations of SSL, TLS, and port numbers.