PROBLEM - Mail rate exceed limit

PROBLEM - Mail rate exceed limit

Please, I have a email account in my domain that can't send email because is blocked. 

account: ana.aguiar@adcarreiras.com.br

She didn't send more than 30 emails today but the account is blocked. I need fixed this issue asap. 

Error Message:
"Dear User,

Saída de emails bloqueada. Motivo: Mail rate exceeded limit 

However, we realised that this might have been unintentional. To unblock, please click here.

Thanks,
Zoho Mail Team"

The "click here" link doesnt work, too.