Zoho blocking 1st outgoing email every day

Zoho blocking 1st outgoing email every day

I use an email client (Becky) on my Windows computer and retrieve my email from the Zoho server using POP3.  About a month ago I began to get a "451 null" error message whenever I sent out the 1st email of the day using my Zoho address.  I have to go to the OUTBOX on my email program and resend the email - making no other changes - and it goes through without a problem.  Here's the error message:

  

Any idea what's going on?